| Date of match | Type of match | Name of team | Name of team | Score | Attendance |
| 23 August 1890 | Scottish League | Heart of Midlothian | Celtic | 0-5 | - |
| 13 September 1890 | Scottish League | Heart of Midlothian | Cowlairs | 4-0 | - |
| 25 October 1890 | Scottish League | Heart of Midlothian | Vale of Leven | 8-1 | - |
| 24 January 1891 | Scottish League | Heart of Midlothian | Rangers | 0-1 | - |
| 14 February 1891 | Scottish League | Heart of Midlothian | Cambuslang | 2-2 | - |
| 21 February 1891 | Scottish League | Heart of Midlothian | St Mirren | 1-0 | - |
| 21 March 1891 | Scottish League | Heart of Midlothian | 3rd Lanark Rifle Volunteers | 4-1 | - |
| 28 March 1891 | Scottish League | Heart of Midlothian | Abercorn | 1-1 | - |
| 20 April 1891 | Scottish League | Heart of Midlothian | Dumbarton | 0-4 | - |
| 15 August 1891 | Scottish League | Heart of Midlothian | Celtic | 3-1 | - |
| 29 August 1891 | Scottish League | Heart of Midlothian | Dumbarton | 3-1 | - |
| 12 September 1891 | Scottish League | Heart of Midlothian | Renton | 4-2 | - |
| 21 September 1891 | Scottish League | Heart of Midlothian | Abercorn | 2-1 | - |
| 26 September 1891 | Scottish League | Heart of Midlothian | 3rd Lanark Rifle Volunteers | 2-0 | - |
| 10 October 1891 | Scottish League | Heart of Midlothian | St Mirren | 2-2 | - |
| 24 October 1891 | Scottish League | Heart of Midlothian | Leith Athletic | 3-1 | - |
| 28 November 1891 | Scottish FA Cup 1st round (match abandoned after 85 minutes) | Heart of Midlothian | Clyde | 3-1 | - |
| 5 December 1891 | Scottish FA Cup 1st round replay | Heart of Midlothian | Clyde | 8-0 | - |
| 26 December 1891 | Scottish League | Heart of Midlothian | Cambuslang | 1-0 | - |
| 30 January 1892 | Scottish FA Cup quarter-final replay | Heart of Midlothian | Renton | 2-2 | - |
| 19 March 1892 | Scottish League | Heart of Midlothian | Vale of Leven | 7-0 | - |
| 26 March 1892 | Home Championship | Scotland | Wales | 6-1 | 1,200 |
| 16 April 1892 | Scottish League | Heart of Midlothian | Clyde | 2-1 | - |
| 23 April 1892 | Scottish League | Heart of Midlothian | Rangers | 3-2 | - |
| 27 August 1892 | Scottish League | Heart of Midlothian | Celtic | 3-1 | - |
| 10 September 1892 | Scottish League | Heart of Midlothian | Renton | 2-2 | - |
| 24 September 1892 | Scottish League | Heart of Midlothian | St Mirren | 4-0 | - |
| 8 October 1892 | Scottish League | Heart of Midlothian | Dumbarton | 1-3 | - |
| 17 December 1892 | Scottish FA Cup 1st round replay | Heart of Midlothian | Stenhousemuir | 8-0 | - |
| 4 February 1893 | Scottish FA Cup quarter-final | Heart of Midlothian | Queen's Park | 1-1 | - |
| 4 March 1893 | Scottish League | Heart of Midlothian | 3rd Lanark Rifle Volunteers | 2-2 | - |
| 11 March 1893 | Scottish League | Heart of Midlothian | Abercorn | 3-1 | - |
| 18 March 1893 | Scottish League | Heart of Midlothian | Rangers | 1-2 | - |
| 15 April 1893 | Scottish League | Heart of Midlothian | Leith Athletic | 3-1 | - |
| 29 April 1893 | Scottish League | Heart of Midlothian | Clyde | 2-3 | - |
| 3 March 1906 | Home Championship | Scotland | Wales | 0-2 | 25,000 |
| 2 March 1912 | Home Championship | Scotland | Wales | 1-0 | 32,000 |
| 15 August 1924 | Scottish Foobtall League Division One | Hibernian | Partick Thistle | 3-2 | - |
| 16 August 1924 | Scottish Football League Division Two | St Bernard's | Armadale | 3-2 | - |
| 29 August 1924 | Scottish Football League Division One | Hibernian | Motherwell | 1-0 | - |
| 30 August 1924 | Scottish Football League Division Two | St Bernard's | East Stirlingshire | 3-4 | - |
| 13 September 1924 | Scottish Football League Division Two | St Bernard's | Alloa Athletic | 1-0 | - |
| 27 September 1924 | Scottish Football League Division Two | St Bernard's | Dunfermline Athletic | 3-0 | - |
| 11 October 1924 | Scottish Football League Division Two | St Bernard's | Dumbarton | 2-1 | 3,000 |
| 25 October 1924 | Scottish Football League Division Two | St Bernard's | Clydebank | 1-2 | - |
| 1 November 1924 | Scottish Football League Division Two | St Bernard's | Forfar Athletic | 2-1 | - |
| 14 February 1925 | Home Championship | Scotland | Wales | 3-1 | 25,000 |
| 26 October 1932 | Home Championship | Scotland | Wales | 2-5 | 31,000 |
| 13 November 1935 | Home Championship | Scotland | Northern Ireland | 2-1 | 30,000 |
| 9 November 1938 | Home Championship | Scotland | Wales | 3-2 | 34,810 |
| 3 September 1975 | Anglo-Scottish Cup Scottish qualifiers 2nd leg | Heart of Midlothian | Queen of the South | 3-1 | 5,000 |
| 1 October 1975 | Anglo-Scottish Cup quarter-final 2nd leg | Heart of Midlothian | Fulham | 2-2 | 14,517 |
| 23 August 1978 | Anglo-Scottish Cup Scottish qualifiers 2nd leg | Heart of Midlothian | Partick Thistle | 0-1 | - |
| 6 August 1980 | Anglo-Scottish Cup Scottish qualifiers 2nd leg | Hear of Midlothian | Airdrieonians | 3-3 | - |
| 25 November 1989 | Scottish Football League Division Two | Berwick Rangers | Kilmarnock | 3-2 | 784 |
| 18 April 1992 | Scottish Football League Division Two | Meadowbank Thistle | Ayr United | 0-1 | 367 |
| 10 October 1998 | European Championship qualifier | Scotland | Estonia | 3-2 | 16,930 |
| 27 May 2003 | International friendly | Scotland | New Zealand | 1-1 | 10,016 |
| 16 October 2018 | UEFA under-21 championship preliminaries | Scotland | England | 0-2 | 4,122 |
